Title:
Ferrocene-Based Ozonide: [CpFeCpCH2NMe3]O3·1.47 NH3, Synthesis and Crystal Structure Analysis
Author(s):
Schmid, Jonas R.; Rennefeld, Oliver R. H.; Wiesner, Anja; Jansen, Martin; Riedel, Sebastian
Year of publication:
2025
Available Date:
2025-09-26T13:00:54Z
Abstract:
The highly reactive ozonide anion could be stabilized for the first time with a ferrocene-based cation resulting in the title compound [CpFeCpCH2NMe3]O3·1.47 NH3. The target compound was thoroughly characterized by X-ray diffraction [P21/c a = 1778.33(8) pm, b = 811.70(4) pm, c = 1111.71(5) pm, β = 91.715(2)°, R = 0.0325, 40301 reflections]. Additionally, infrared spectroscopy as well as quantum chemical calculations of the embedded anion were carried out to further characterize the compound and investigated the O-O bond lengths and O-O-O bond angles of the ozonide anion.
Part of Identifier:
e-ISSN (online): 1521-3749
Keywords:
ferrocene
ozonide
quantum chemistry
radical ions
X-ray diffraction
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Zeitschrift für anorganische und allgemeine Chemie
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie
Comments:
Gefördert aus Open-Access-Mitteln der Freien Universität Berlin.
