Title:
A mixed isocyanide Mn(i) complex and its reduction to a metallate
Author(s):
Claude, Guilhem; Ellwanger, Mathias A.; Grippo, Adam; Hernandez, Ritchie; Figueroa, Joshua R.; Abram, Ulrich
Year of publication:
2025
Available Date:
2025-05-06T08:31:29Z
Abstract:
A stepwise ligand exchange starting from [Mn(CO)5Br] allows the synthesis of the heteroleptic isocyanide manganese(I) complex mer,trans-[Mn(CNp-FArDArF2)3(CNtBu)2Br] (DArF = 3,5-(CF3)2C6H3, tBu = tert-butyl). Subsequent reduction gave the first heteroleptic isocyanide manganese(−1) complex, [K(18-crown-6)][Mn(CNp-FArDArF2)3(CNtBu)2], exhibiting a five-coordinate, trigonal bipyramidal coordination sphere.
Part of Identifier:
e-ISSN (online): 1477-9234
Keywords:
isocyanide manganese(I) complex
reduction
metallate
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Dalton Transactions
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie
