Title:
Improved access to polythioesters by heterobimetallic aluminium catalysis
Author(s):
Manjunatha, Bhargav R.; Stühler, Merlin R.; Quick, Luise; Plajer, Alex J.
Year of publication:
2024
Available Date:
2024-05-06T07:18:49Z
Abstract:
Bimetallic Al(III) catalysis mediates thioanhydride/epoxide copolymerisation at greatly improved rates and monomer tolerance than analogous Cr(III) catalysis. Moving to sulfurated monomers furthermore generally improves rates and selectivites.
Part of Identifier:
e-ISSN (online): 1364-548X
Keywords:
polythioesters
heterobimetallic aluminium catalysis
improved access
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Chemical Communications
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie