dc.contributor.author
Deng, Guohai
dc.contributor.author
Reimann, Marc
dc.contributor.author
Müller, Carsten
dc.contributor.author
Lu, Yan
dc.contributor.author
Kaupp, Martin
dc.contributor.author
Riedel, Sebastian
dc.date.accessioned
2024-04-22T08:13:00Z
dc.date.available
2024-04-22T08:13:00Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/43103
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-42818
dc.description.abstract
The perfluorinated silylphosphinidene, F3SiP, in the triplet ground state is generated by the reaction of laser-ablated silicon atoms with PF3 in solid neon and argon matrices. The reactions proceed with the initial formation of a silicon trifluorophosphine complex, F3PSi, in the triplet ground state, and a more stable inserted phosphasilene, FPSiF2, in the singlet ground state upon deposition. The trifluorosilylphosphinidene was formed through F-migration reactions of FPSiF2 and F3PSi following a two-state mechanism under irradiation with visible light (λ = 470 nm) and full arc light (λ > 220 nm), respectively. High-level quantum-chemical methods support the identification of F3PSi, FPSiF2, and F3SiP by matrix-isolation IR spectroscopy.
en
dc.format.extent
7 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
Chemical calculations
en
dc.subject
Molecular structure
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Spectroscopic Identification of Trifluorosilylphosphinidene and Isomeric Phosphasilene and Silicon Trifluorophosphine Complex
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1021/acs.inorgchem.4c00135
dcterms.bibliographicCitation.journaltitle
Inorganic Chemistry
dcterms.bibliographicCitation.number
16
dcterms.bibliographicCitation.pagestart
7286
dcterms.bibliographicCitation.pageend
7292
dcterms.bibliographicCitation.volume
63
dcterms.bibliographicCitation.url
https://doi.org/10.1021/acs.inorgchem.4c00135
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
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refubium.funding
ACS Publications
refubium.note.author
Die Publikation wurde aus Open Access Publikationsgeldern der Freien Universität Berlin gefördert.
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1520-510X