dc.contributor.author
Kub, Nico G.
dc.contributor.author
Sievers, Robin
dc.contributor.author
Parche, Joshua
dc.contributor.author
Malischewski, Moritz
dc.date.accessioned
2024-05-06T06:56:26Z
dc.date.available
2024-05-06T06:56:26Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/42602
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-42326
dc.description.abstract
Triphenylpnictogens EPh3 (E = N, P, As, Sb, Bi) are able to displace the perfluorinated Cp* ligand in [Rh(COD)(C5(CF3)5)] (COD = 1,5-cyclooctadiene) in up to quantitative yield. The resulting ionic products contain [C5(CF3)5]− as uncoordinated counter anion. The cations feature [Rh(COD)]+ fragments, coordinated by one (N, Bi), two (P, As) or three (Sb) triphenylpnictogen moieties. Whereas coordination via the pnictogen is observed for P, As and Sb, π-coordination of the aryl rings is observed for N and Bi.
en
dc.format.extent
6 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
cyclopentadienyl ligands
en
dc.subject
fluorinated ligands
en
dc.subject
arene ligands
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Substitution Lability of the Perfluorinated Cp* Ligand in [Rh(COD)(C5(CF3)5)] towards Triphenylpnictogens EPh3 (E = N, P, As, Sb, Bi)
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.articlenumber
e202400427
dcterms.bibliographicCitation.doi
10.1002/chem.202400427
dcterms.bibliographicCitation.journaltitle
Chemistry – A European Journal
dcterms.bibliographicCitation.number
23
dcterms.bibliographicCitation.volume
30
dcterms.bibliographicCitation.url
https://doi.org/10.1002/chem.202400427
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
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refubium.funding
DEAL Wiley
refubium.note.author
Die Publikation wurde aus Open Access Publikationsgeldern der Freien Universität Berlin gefördert.
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1521-3765