Title:
[Xe(OTeF5)(pyF)]+: a strong oxidizing xenonium(ii) teflate cation with N-donor bases
Author(s):
Toraman, Ahmet N.; Fischer, Lukas; Pérez-Bitrián, Alberto; Wiesner, Anja; Hoffmann, Kurt F.; Riedel, Sebastian
Year of publication:
2024
Available Date:
2024-02-22T10:02:12Z
Abstract:
Herein we report on the formation of the adduct salts [Xe(OTeF5)(pyF)][Al(OTeF5)4] (pyF = C5F5N, C5H3F2N) by abstraction of an –OTeF5 group from Xe(OTeF5)2 with the Lewis superacid Al(OTeF5)3 and subsequent adduct formation of the generated [XeOTeF5]+ cation with fluorinated pyridines. These salts represent the first xenonium cations with the weakly coordinating [Al(OTeF5)4]− anion. The strong oxidizing property of these compounds is further assessed.
Part of Identifier:
e-ISSN (online): 1364-548X
Keywords:
adduct salts
xenonium cations
strong oxidizing property
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Chemical Communications
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie
