dc.contributor.author
Kleoff, Merlin
dc.contributor.author
Voßnacker, Patrick
dc.contributor.author
Riedel, Sebastian
dc.date.accessioned
2023-04-12T07:17:38Z
dc.date.available
2023-04-12T07:17:38Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/38018
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-37734
dc.description.abstract
Chlorine plays a central role for the industrial production of numerous materials with global relevance. More recently, polychlorides have been evolved from an area of academic interest to a research topic with enormous industrial potential. In this minireview, the value of trichlorides for chlorine storage and chlorination reactions are outlined. Particularly, the inexpensive ionic liquid [NEt3Me][Cl3] shows a similar and sometimes even advantageous reactivity compared to chlorine gas, while offering a superior safety profile. Used as a chlorine storage, [NEt3Me][Cl3] could help to overcome the current limitations of storing and transporting chlorine in larger quantities. Thus, trichlorides could become a key technique for the flexibilization of the chlorine production enabling an exploitation of renewable, yet fluctuating, electrical energy. As the loaded storage, [NEt3Me][Cl3], is a proven chlorination reagent, it could directly be employed for downstream processes, paving the path to a more practical and safer chlorine industry.
en
dc.format.extent
9 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by-nc/4.0/
dc.subject
Industrial Chemistry
en
dc.subject
Ionic Liquids
en
dc.subject
Polychlorides
en
dc.subject
Synthetic Methods
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
The Rise of Trichlorides Enabling an Improved Chlorine Technology
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.articlenumber
e202216586
dcterms.bibliographicCitation.doi
10.1002/anie.202216586
dcterms.bibliographicCitation.journaltitle
Angewandte Chemie International Edition
dcterms.bibliographicCitation.number
17
dcterms.bibliographicCitation.volume
62
dcterms.bibliographicCitation.url
https://doi.org/10.1002/anie.202216586
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.funding
DEAL Wiley
refubium.note.author
Die Publikation wurde aus Open Access Publikationsgeldern der Freien Universität Berlin gefördert.
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1521-3773