dc.contributor.author
Kleoff, Merlin
dc.contributor.author
Voßnacker, Patrick
dc.contributor.author
Riedel, Sebastian
dc.date.accessioned
2023-04-12T07:17:38Z
dc.date.available
2023-04-12T07:17:38Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/38018
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-37734
dc.description.abstract
Chlorine plays a central role for the industrial production of numerous materials with global relevance. More recently, polychlorides have been evolved from an area of academic interest to a research topic with enormous industrial potential. In this minireview, the value of trichlorides for chlorine storage and chlorination reactions are outlined. Particularly, the inexpensive ionic liquid [NEt3Me][Cl3] shows a similar and sometimes even advantageous reactivity compared to chlorine gas, while offering a superior safety profile. Used as a chlorine storage, [NEt3Me][Cl3] could help to overcome the current limitations of storing and transporting chlorine in larger quantities. Thus, trichlorides could become a key technique for the flexibilization of the chlorine production enabling an exploitation of renewable, yet fluctuating, electrical energy. As the loaded storage, [NEt3Me][Cl3], is a proven chlorination reagent, it could directly be employed for downstream processes, paving the path to a more practical and safer chlorine industry.
en
dc.format.extent
9 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by-nc/4.0/
dc.subject
Industrial Chemistry
en
dc.subject
Ionic Liquids
en
dc.subject
Polychlorides
en
dc.subject
Synthetic Methods
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
The Rise of Trichlorides Enabling an Improved Chlorine Technology
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.articlenumber
e202216586
dcterms.bibliographicCitation.doi
10.1002/anie.202216586
dcterms.bibliographicCitation.journaltitle
Angewandte Chemie International Edition
dcterms.bibliographicCitation.number
17
dcterms.bibliographicCitation.volume
62
dcterms.bibliographicCitation.url
https://doi.org/10.1002/anie.202216586
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
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refubium.funding
DEAL Wiley
refubium.note.author
Die Publikation wurde aus Open Access Publikationsgeldern der Freien Universität Berlin gefördert.
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1521-3773