Title:
Thioanhydride/isothiocyanate/epoxide ring-opening terpolymerisation: sequence selective enchainment of monomer mixtures and switchable catalysis
Author(s):
Silbernagl, Dorothee; Sturm, Heinz; Plajer, Alex J.
Year of publication:
2022
Available Date:
2022-08-05T12:10:23Z
Abstract:
We report a new sequence selective terpolymerisation in which three monomers (butylene oxide (BO) A, PhNCS B and phtalic thioanhydride (PTA) C) are selectively enchained into an (ABA′C)n sequence. PTA/PhNCS/BO ring-opening terpolymerisation ROTERP can be coupled with CS2 ROTERP to generate tetrapolymers and with εDL ROP in switchable catalysis for blockpolymer synthesis.
Part of Identifier:
e-ISSN (online): 1759-9962
Keywords:
terpolymerisation
sequence selective enchainment
monomer mixtures
switchable catalysis
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Polymer Chemistry
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie
