Title:
[{TcI(NO)(LOMe)(PPh3)Cl}2Ag](PF6) and [TcII(NO)(LOMe)(PPh3)Cl](PF6): Two Unusual Technetium Complexes with a “Kläui-type” Ligand
Author(s):
Jungfer, Maximilian Roca; Ernst, Moritz Johannes; Hagenbach, Adelheid; Abram, Ulrich
Year of publication:
2022
Available Date:
2022-02-16T09:49:21Z
Abstract:
The reaction of [TcI(NO)(LOMe)(PPh3)Cl] ({LOMe}−=η5-cyclopentadienyltris(dimethyl phosphito-P)cobaltate(III)) with Ag(PF6) gives two unexpected products: the dimeric technetium(I) complex [{Tc(NO)(LOMe)(PPh3)Cl}2Ag](PF6) with a central Ag+ ion and the cationic Tc(II) compound [Tc(NO)(LOMe)(PPh3)Cl](PF6). The products have been studied spectroscopically and by X-ray diffraction.
Part of Identifier:
e-ISSN (online): 1521-3749
Keywords:
Technetium
nitrosyl complexes
EPR
tripod ligands
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Zeitschrift für anorganische und allgemeine Chemie
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie
Comments:
Die Publikation wurde aus Open Access Publikationsgeldern der Freien Universität Berlin gefördert.