Title:
Au(i)-mediated N2-elimination from triazaphospholes: a one-pot synthesis of novel N2P2-heterocycles
Author(s):
Yue, Erlin; Dettling, Lea; Sklorz, Julian A. W.; Kaiser, Selina; Weber, Manuela; Müller, Christian
Year of publication:
2021
Available Date:
2022-01-06T11:07:22Z
Abstract:
Novel tosyl- and mesitylsulfonyl-substituted triazaphospholes were synthesized and structurally characterized. In an attempt to prepare the corresponding Au(I)-complexes with stoichiometric amounts of AuCl·S(CH3)2, cyclo-1,3-diphospha(III)-2,4-diazane-AuCl-complexes were obtained instead. Our here presented results offer a new strategy for preparing such coordination compounds selectively in a one-pot approach.
Part of Identifier:
e-ISSN (online): 1364-548X
Keywords:
coordination chemistry
phosphorus-compounds
crystal-structures
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Chemical Communications
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie
