dc.contributor.author
Li, Bo
dc.contributor.author
Hildebrandt, Sarah
dc.contributor.author
Hagenbach, Adelheid
dc.contributor.author
Abram, Ulrich
dc.date.accessioned
2021-05-12T07:42:32Z
dc.date.available
2021-05-12T07:42:32Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/30473
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-30213
dc.description.abstract
Two potentially tripodal ligands, tris(1-phenyl-1H-1,2,3-triazol-4-yl)phosphine oxide (OP((1,2,3)Tz(1-Ph))(3)) and tris(1-benzyl-1H-1,2,3-triazol-4-yl)phosphine oxide (OP((1,2,3)Tz(1-benz))(3)), were used in reactions with [Re(CO)(5)Br] and (NEt4)(2)[Tc(CO)(3)Cl-3]. While the formation of rhenium complexes with bidentate and tridentate coordinated phosphine oxides was observed, for technetium only cationic complexes with tripodal coordinated OP((1,2,3)Tz(1-R)) ligands were isolated. The products have been characterized spectroscopically and by single crystal X-ray diffraction.
en
dc.format.extent
7 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by-nc/4.0/
dc.subject
tris(azolyl)phosphine oxides
en
dc.subject
tricarbonylrhenium(I)
en
dc.subject
tricarbonyltechnetium(I)
en
dc.subject
tripod ligands
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Tricarbonylrhenium(I) and ‐technetium(I) Complexes with Tris(1,2,3‐triazolyl)phosphine Oxides
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1002/zaac.202100010
dcterms.bibliographicCitation.journaltitle
Zeitschrift für anorganische und allgemeine Chemie
dcterms.bibliographicCitation.number
10
dcterms.bibliographicCitation.pagestart
1070
dcterms.bibliographicCitation.pageend
1076
dcterms.bibliographicCitation.volume
647
dcterms.bibliographicCitation.url
https://doi.org/10.1002/zaac.202100010
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.funding
DEAL Wiley
refubium.note.author
Die Publikation wurde aus Open Access Publikationsgeldern der Freien Universität Berlin gefördert.
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1521-3749
refubium.resourceType.provider
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