Title:
Benzothiazolium salts as reagents for the deoxygenative perfluoroalkylthiolation of alcohols
Author(s):
Ariamajd, Armin; Gerwien, Nils J.; Schwabe, Benjamin; Dix, Stefan; Hopkinson, Matthew N.
Year of publication:
2021
Available Date:
2021-03-12T15:14:20Z
Abstract:
A series of 2-(perfluoroalkylthio)benzothiazolium (BT-SRF) salts have been synthesized that serve as convenient sources of hitherto underexplored perfluoroalkylthiolate anions. An investigation of their reactivity in a deoxygenative nucleophilic substitution reaction led to the development of an unprecedented process that provides pentafluoroethyl and heptafluoropropyl thioethers directly from readily available alcohols.
Part of Identifier:
e-ISSN (online): 1860-5397
Keywords:
alcohols
benzothiazolium salts
deoxygenative reactions
fluorine
perfluoroalkylthiolation
thioethers
DDC-Classification:
547 Organische Chemie
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Beilstein Journal of Organic Chemistry
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie