dc.contributor.author
Ariamajd, Armin
dc.contributor.author
Gerwien, Nils J.
dc.contributor.author
Schwabe, Benjamin
dc.contributor.author
Dix, Stefan
dc.contributor.author
Hopkinson, Matthew N.
dc.date.accessioned
2021-03-12T15:14:20Z
dc.date.available
2021-03-12T15:14:20Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/29921
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-29663
dc.description.abstract
A series of 2-(perfluoroalkylthio)benzothiazolium (BT-SRF) salts have been synthesized that serve as convenient sources of hitherto underexplored perfluoroalkylthiolate anions. An investigation of their reactivity in a deoxygenative nucleophilic substitution reaction led to the development of an unprecedented process that provides pentafluoroethyl and heptafluoropropyl thioethers directly from readily available alcohols.
en
dc.format.extent
6 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
benzothiazolium salts
en
dc.subject
deoxygenative reactions
en
dc.subject
perfluoroalkylthiolation
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::547 Organische Chemie
dc.title
Benzothiazolium salts as reagents for the deoxygenative perfluoroalkylthiolation of alcohols
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.3762/bjoc.17.8
dcterms.bibliographicCitation.journaltitle
Beilstein Journal of Organic Chemistry
dcterms.bibliographicCitation.pagestart
83
dcterms.bibliographicCitation.pageend
88
dcterms.bibliographicCitation.volume
17
dcterms.bibliographicCitation.url
https://doi.org/10.3762/bjoc.17.8
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1860-5397
refubium.resourceType.provider
WoS-Alert