Title:
Soluble Fluoridobromates as Well‐Behaved Strong Fluorination Reagents
Author(s):
Schmid, Jonas R.; Pröhm, Patrick; Voßnacker, Patrick; Thiele, Günter; Ellwanger, Mathias; Steinhauer, Simon; Riedel, Sebastian
Year of publication:
2020
Available Date:
2021-01-11T11:55:09Z
Abstract:
We present a facile synthesis of the soluble fluoridobromates [NEt3Me][BrF4] and [NEt3Me][Br2F7] via fluorination of the corresponding bromide salts in acetonitrile, propionitrile or bromine. We structurally characterized the [BrF2]– anion, an intermediate during the synthesis, for the first time. Additionally, the dissolution of noble metals to form the corresponding halometallates as well as the application of [NEt3Me][BrF4] as a fluorination agent for disulfides to form pentafluorosulfanyls was studied.
Part of Identifier:
e-ISSN (online): 1099-0682
Keywords:
Fluoridobromates
DDC-Classification:
572 Biochemie
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
European Journal of Inorganic Chemistry
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie
Comments:
Die Publikation wurde aus Open Access Publikationsgeldern der Freien Universität Berlin gefördert.