Title:
Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9-Phospha- and 9-Arsena-Fluorenium Ions
Author(s):
Olaru, Marian; Duvinage, Daniel; Nass, Yannik; Malaspina, Lorraine A.; Mebs, Stefan; Beckmann, Jens
Year of publication:
2020
Available Date:
2020-10-28T09:07:06Z
Abstract:
Transient phosphenium and arsenium ions, generated by fluoride abstraction from bis(m-terphenyl)fluoropnictogens, underwent intramolecular electrophilic attack prior to methyl group migration and gave rise to isolable 9-phospha- and 9-arsena-fluorenium ions.
Part of Identifier:
ISSN (print): 1433-7851
e-ISSN (online): 1521-3773
Keywords:
arenium ions
arsoles
m-terphenyl compounds
phospholes
pnictogenium ions
DDC-Classification:
530 Physik
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Angewandte Chemie International Edition
Department/institution:
Physik
Institut für Experimentalphysik
