dc.contributor.author
Meyer, Fabio
dc.contributor.author
Hupf, Emanuel
dc.contributor.author
Lork, Enno
dc.contributor.author
Grabowsky, Simon
dc.contributor.author
Mebs, Stefan
dc.contributor.author
Beckmann, Jens
dc.date.accessioned
2020-11-05T14:27:03Z
dc.date.available
2020-11-05T14:27:03Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/28626
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-28375
dc.description.abstract
The synthesis of the new ligand bis(6-diphenylphosphinoacenaphth-5-yl)sulfoxide, [6-(Ph2P)-5-Ace-6](2)-SO (1), is presented along with six transition metal complexes thereof, namely,1 center dot MCl (M = Rh, Cu, Ag, Au) and1 center dot MCl2(M = Ni, Pd). Within these novel complexes, close metal-sulfur distances are observed and the nature of the M-S coordination, as well as the response of the(+)S-O(-)bond, are investigated in detail with a set of spectroscopic, crystallographic and real-space bonding indicators.
en
dc.format.extent
8 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
Bond Analysis
en
dc.subject
Pincer Ligands
en
dc.subject
Transition metal complexes
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::546 Anorganische Chemie
dc.title
Bis(6‐diphenylphosphino‐acenaphth‐5‐yl)sulfoxide: A New Ligand for Late Transition Metal Complexes
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1002/ejic.202000610
dcterms.bibliographicCitation.journaltitle
European Journal of Inorganic Chemistry
dcterms.bibliographicCitation.number
40
dcterms.bibliographicCitation.pagestart
3829
dcterms.bibliographicCitation.pageend
3836
dcterms.bibliographicCitation.volume
2020
dcterms.bibliographicCitation.url
https://doi.org/10.1002/ejic.202000610
refubium.affiliation
Physik
refubium.affiliation.other
Institut für Experimentalphysik
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refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1099-0682
refubium.resourceType.provider
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