dc.contributor.author
Nissen, Jan H.
dc.contributor.author
Drews, Thomas
dc.contributor.author
Schröder, Benjamin
dc.contributor.author
Beckers, Helmut
dc.contributor.author
Steinhauer, Simon
dc.contributor.author
Riedel, Sebastian
dc.date.accessioned
2019-11-19T12:12:50Z
dc.date.available
2019-11-19T12:12:50Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/25960
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-25718
dc.description.abstract
A more convenient synthesis of the perfluoro alkyl hypofluorite (F3C)3COF as well as the hitherto unknown (C2F5)(F3C)2COF compound is reported. Both hypofluorites can be prepared by use of the corresponding tertiary alcohols RFOH and elemental fluorine in the presence of CsF. An appropriate access to these highly reactive hypofluorites is crucial. The hypofluorites are then transferred into their corresponding perfluoro bisalkyl peroxides RFOORF [RF=(F3C)3C, (C2F5)(F3C)2C] by treatment with partially fluorinated silver wool. NMR, gas‐phase infrared, and solid‐state Raman spectra of the perfluoro bisalkyl peroxides are presented and their chemical properties are discussed.
en
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
Fluorine Chemistry
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Perfluoro Alkyl Hypofluorites and Peroxides Revisited
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1002/chem.201903620
dcterms.bibliographicCitation.journaltitle
Chemistry - A European Journal
dcterms.bibliographicCitation.number
64
dcterms.bibliographicCitation.pagestart
14721
dcterms.bibliographicCitation.pageend
14727
dcterms.bibliographicCitation.volume
25
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.funding
DEAL Wiley
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access