dc.contributor.author
Redeker, Frenio A.
dc.contributor.author
Ellwanger, Mathias A.
dc.contributor.author
Beckers, Helmut
dc.contributor.author
Riedel, Sebastian
dc.date.accessioned
2019-11-15T11:35:26Z
dc.date.available
2019-11-15T11:35:26Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/25941
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-25701
dc.description.abstract
Molecular alkali tetrafluorido aurate ion pairs M[AuF4] (M=K, Rb, Cs) are produced by co‐deposition of IR laser‐ablated AuF3 and MF in solid neon under cryogenic conditions. This method also yields molecular AuF3 and its dimer Au2F6. The products are characterized by their Au–F stretching bands and high‐level quantum‐chemical calculations at the CCSD(T)/triple‐ζ level of theory. Structural changes in AuF4− associated with the coordination of the anion to different alkali cations are proven spectroscopically and discussed.
en
dc.format.extent
4 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
fluorine chemistry
en
dc.subject
gold chemistry
en
dc.subject
laser-ablation
en
dc.subject
matrix-isolation spectroscopy
en
dc.subject
quantum-chemical calculations
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::546 Anorganische Chemie
dc.title
Investigation of molecular alkali tetrafluorido aurates by matrix‐isolation spectroscopy
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1002/chem.201904335
dcterms.bibliographicCitation.journaltitle
Chemistry - a European journal
dcterms.bibliographicCitation.volume
25
dcterms.bibliographicCitation.url
https://doi.org/10.1002/chem.201904335
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Anorganische Chemie
refubium.funding
DEAL Wiley
refubium.note.author
Die Publikation wurde von der Freien Universität Berlin finanziert.
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
0016-7037
refubium.resourceType.provider
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