Title:
{Tc(NO)(Cp)(PPh3)}+ – a novel technetium(I) core
Author(s):
Ackermann, Janine; Hagenbach, A.; Abram, U.
Year of publication:
2016
Available Date:
2016-10-12T08:20:43.062Z
Abstract:
Reactions between [TcI(NO)X2(PPh3)2(CH3CN)] complexes (X = Cl, Br) and KCp
form the pseudotetrahedral organotechnetium compounds [TcI(NO)(Cp)(PPh3)X].
The halide ligands can readily be replaced by other halides or organometallic
ligands giving access to a novel family of technetium(I) compounds with the
robust {Tc(NO)(Cp)(PPh3)}+ core.
DDC-Classification:
540 Chemie
Publication Type:
Wissenschaftlicher Artikel
Also published in:
Chem. Commun. - 52 (2016), 67, S. 10285-10288
URL of the Original Publication:
DOI of the Original Publication:
Department/institution:
Biologie, Chemie, Pharmazie
Comments:
Der Artikel wurde in einer Open-Access-Zeitschrift publiziert.