dc.contributor.author
Willenbockel, Martin
dc.contributor.author
Maurer, Reinhard J.
dc.contributor.author
Bronner, Christopher
dc.contributor.author
Schulze, Michael
dc.contributor.author
Stadtmüller, Benjamin
dc.contributor.author
Soubatch, Serguei
dc.contributor.author
Tegeder, Petra
dc.contributor.author
Reuter, Karsten
dc.contributor.author
Tautz, F. Stefan
dc.date.accessioned
2018-06-08T07:16:10Z
dc.date.available
2016-02-11
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/17539
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-21423
dc.description.abstract
We investigate the surface-catalyzed dissociation of the archetypal molecular
switch azobenzene on the Cu(111) surface. Based on X-ray photoelectron
spectroscopy, normal incidence X-ray standing waves and density functional
theory calculations a detailed picture of the coverage-induced formation of
phenyl nitrene from azobenzene is presented. Furthermore, a comparison to the
azobenzene/Ag(111) interface provides insight into the driving force behind
the dissociation on Cu(111). The quantitative decay of azobenzene paves the
way for the creation of a defect free, covalently bonded monolayer. Our work
suggests a route of surface functionalization via suitable azobenzene
derivatives and the on surface synthesis concept, allowing for the creation of
complex immobilized molecular systems.
en
dc.rights.uri
http://creativecommons.org/licenses/by/3.0/
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie
dc.title
Coverage-driven dissociation of azobenzene on Cu(111)
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation
Chem. Commun. - 51 (2015), 83, S. 15324-15327
dc.identifier.sepid
48410
dc.title.subtitle
a route towards defined surface functionalization
dcterms.bibliographicCitation.doi
10.1039/C5CC05003K
dcterms.bibliographicCitation.url
http://dx.doi.org/10.1039/C5CC05003K
refubium.affiliation
Physik
de
refubium.affiliation.other
Institut für Experimentalphysik
refubium.mycore.fudocsId
FUDOCS_document_000000023865
refubium.resourceType.isindependentpub
no
refubium.mycore.derivateId
FUDOCS_derivate_000000005960
dcterms.accessRights.openaire
open access
dcterms.isPartOf.issn
1359-7345