Title:
Tuning the electronic effects of aromatic phosphorus heterocycles
Subtitle:
An unprecedented phosphinine with significant P(π)-donor properties
Author(s):
Loibl, A.; De Krom, I.; Pidko, E.A.; Weber, M.; Wiecko, J.; Müller, C.
Year of publication:
2014
Available Date:
2014-08-18T19:16:34.019Z
Abstract:
A hitherto unprecedented electronic situation has been observed for a
substituted, pyridyl-functionalized phosphinine. In contrast to previous
studies, this compound shows considerable π-donor properties as the result of
the rather strong +M effect of the CH3S-substituent, changing the electronic
properties of this low-coordinate and aromatic phosphorus heterocycle
substantially.
DDC-Classification:
540 Chemie
Publication Type:
Wissenschaftlicher Artikel
Also published in:
Chemical Communications. - 50 (2014), 64, S. 8842-8844
URL of the Original Publication:
DOI of the Original Publication:
Department/institution:
Biologie, Chemie, Pharmazie
