Title:
A traceless photocleavable linker for the automated glycan assembly of
carbohydrates with free reducing ends
Author(s):
Wilsdorf, M.; Schmidt, D.; Bartetzko, M. P.; Dallabernardina, Pietro; Schuhmacher, F.; Seeberger, P. H.; Pfrengle, F.
Year of publication:
2016
Available Date:
2016-09-27T11:58:46.579Z
Abstract:
We report a traceless photocleavable linker for the automated glycan assembly
of carbohydrates with free reducing ends. The reductive-labile functionality
in the linker tolerates all commonly used reagents and protocols for automated
glycan assembly, as demonstrated with the successful preparation of nine plant
cell wall-related oligosaccharides, and is cleaved by hydrogenolysis.
DDC-Classification:
540 Chemie
Publication Type:
Wissenschaftlicher Artikel
Also published in:
Chemical Communications. - 52 (2016), 66, S. 10187-10189
URL of the Original Publication:
DOI of the Original Publication:
Department/institution:
Biologie, Chemie, Pharmazie
