Haupttitel:
Activation and Fixation of Atmospheric CO2 through a 1,2,3-Triazole-Based Mesoionic Carbene–Borane Adduct
Autor*in:
Neubrand, Maren; Stubbe, Jessica; Rudolf, Richard; Walter, Robert R. M.; Nößler, Maite; Sarkar, Biprajit
Datum der Freigabe:
2025-05-23T08:21:40Z
Abstract:
Capturing atmospheric CO2 and converting it to valuable chemicals are important goals in contemporary science. We present here a simple, transition metal-free triazolylidene–borane adduct that can capture atmospheric CO2 and convert it to formate. Several key intermediates were isolated and characterized by a combination of multinuclear NMR spectroscopy, IR spectroscopy and single crystal X-ray diffraction. A first closed cycle for the conversion of CO2 to formic acid by using the aforementioned triazolylidene–borane compound is presented as well.
Teil des Identifiers:
e-ISSN (online): 1521-3765
Freie Schlagwörter:
boranes
CO2 capture
CO2 fixation
formic acid
mesoionic carbenes
DDC-Klassifikation:
540 Chemie und zugeordnete Wissenschaften
Publikationstyp:
Wissenschaftlicher Artikel
Zeitschrift:
Chemistry – A European Journal
Fachbereich/Einrichtung:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie
Anmerkungen:
Gefördert aus Open-Access-Mitteln der Freien Universität Berlin.