Title:
On the Facile Synthesis of Triazaarsoles Using Acyclic Precursors
Author(s):
Szych, Lilian Sophie; Frost, Daniel Sebastian; Ernst, Moritz Johannes; Bresien, Jonas; Weber, Manuela; Puhlmann, Annelie; Sander, Luise; Müller, Christian
Year of publication:
2025
Available Date:
2025-05-23T08:05:22Z
Abstract:
Easily accessible dichloroarsanes are suitable precursors for the synthesis of rarely explored triazaarsoles, the arsenic analogues of tetrazoles and triazaphospholes. Calculations on the DFT level gave insight into the electronic structure of such planar compounds, indicating a high degree of aromaticity. Our preliminary investigations pave the way for accessing and investigating a whole variety of new heterocycles, that contain a low-coordinated arsenic atom.
Part of Identifier:
e-ISSN (online): 1521-3765
Keywords:
Phosphorus
arsenic
Heterocycles
DFT-calculations
X-ray crystallography
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Chemistry - A European Journal
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie
Comments:
Gefördert aus Open-Access-Mitteln der Freien Universität Berlin.