Title:
Precise construction of weather-sensitive poly(ester-alt-thioesters) from phthalic thioanhydride and oxetane
Author(s):
Fornacon-Wood, Christoph; Stühler, Merlin R.; Gallizioli, Cesare; Manjunatha, Bhargav R.; Wachtendorf, Volker; Schartel, Bernhard; Plajer, Alex J.
Year of publication:
2023
Available Date:
2024-01-16T11:55:37Z
Abstract:
We report the selective ring opening copolymerisation (ROCOP) of oxetane and phthalic thioanhydride by a heterobimetallic Cr(III)K catalyst precisely yielding semi-crystalline alternating poly(ester-alt-thioesters) which show improved degradability due to the thioester links in the polymer backbone.
Part of Identifier:
e-ISSN (online): 1364-548X
Keywords:
selective ring opening copolymerisation
oxetane
phthalic thioanhydride
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Chemical Communications
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie