The African continent is rarely the focus of microplastics research, although the ubiquity of microplastics in the environment is undisputed and still increasing. Due to the high production and use of plastic products and the partial lack of recycling systems in many parts of the African continent, it can be assumed that microplastic particles are already present in limnic and terrestrial ecosystems. Few studies, mainly from South Africa and the Northern African region, show a contamination with microplastics, especially in marine environments. This study aims to explore the presence and composition of microplastics in fluvial sediments of the major catchments in Namibia with a regional focus on the Iishana system in Northern Namibia, as one of the most densely populated areas in the country. In March 2019 and March 2021, at the end of the rainy seasons, sediments from the Iishana system and of the largest river catchments were sampled. Extraction was performed by density separation using the Microplastic Sediment Separator (MPSS) with the separation solution sodium chloride (density of 1.20 g/cm3). The particle size was determined by filtration and fractionation, and the polymer type by measurement with ATR-FTIR spectroscopy (minimum particle size 0.3 mm). Microplastics were found in the sediments of each river system, most of the particles in the Iishana system (average of 13.2 particles/kg dry weight). The perennial, the ephemeral rivers, and the Iishana system are similar concerning polymer type and particle size. Polyethylene and polypropylene were the dominant polymer types. Most of the particles were found in the size fractions 0.3 – 0.5 mm and 0.5 – 1.0 mm. The particles were found mainly as fragments and films, the majority transparent and brown.
