Title:
C-H activation in IrIII and N-demethylation in PtII complexes with mesoionic
carbene ligands
Subtitle:
examples of monometallic, homobimetallic and heterobimetallic complexes
Author(s):
Maity, Ramananda; Tichter, Tim; Meer, Margarethe van der; Sarkar, Biprajit
Year of publication:
2015
Available Date:
2016-11-10T12:16:10.731Z
Abstract:
Mononuclear PtII and the first dinuclear PtII complexes along with a
cyclometalated heterobimetallic IrIII/PdII complex bearing mesoionic carbene
donor ligands are presented starting from the same bis-triazolium salt. The
mononuclear PtII complex possesses a free triazole moiety which is generated
from the corresponding triazolium salt through an N-demethylation reaction,
whereas the mononuclear IrIII complex features an unreacted triazolium unit.
DDC-Classification:
540 Chemie
Publication Type:
Wissenschaftlicher Artikel
Also published in:
Dalton Transactions. - 44 (2015), 42, S. 18311-18315
URL of the Original Publication:
DOI of the Original Publication:
Department/institution:
Biologie, Chemie, Pharmazie