Haupttitel:
Comparison of phase transfer agents in the aqueous biphasic hydroformylation
of higher alkenes
Autor*in:
Nowothnick, Henriette; Rost, Anke; Hamerla, Tobias; Schomäcker, Reinhard; Müller, Christian; Vogt, Dieter
Datum der Freigabe:
2015-03-10T10:54:32.587Z
Abstract:
The Rh-catalyzed aqueous biphasic hydroformylation with the bidentate ligand
SulfoXantPhos was investigated for different phase transfer agents (PTA). As
such, polymer latices and microemulsions formed by non-ionic surfactants were
used. In general, a higher PTA concentration enhances the reaction progress.
The feasibility of catalyst recycling by simple phase separation is shown in
principle. The Rh losses are low in the surfactant system and promising for a
technical approach.
Teil des Identifiers:
ISSN (print): 2044-4753
DDC-Klassifikation:
540 Chemie
Publikationstyp:
Wissenschaftlicher Artikel
Auch erschienen in:
Catalysis Science & Technology. - 3 (2013), 3, S. 600-605
Fachbereich/Einrichtung:
Biologie, Chemie, Pharmazie
