Title:
Comparison of phase transfer agents in the aqueous biphasic hydroformylation
of higher alkenes
Author(s):
Nowothnick, Henriette; Rost, Anke; Hamerla, Tobias; Schomäcker, Reinhard; Müller, Christian; Vogt, Dieter
Year of publication:
2013
Available Date:
2015-03-10T10:54:32.587Z
Abstract:
The Rh-catalyzed aqueous biphasic hydroformylation with the bidentate ligand
SulfoXantPhos was investigated for different phase transfer agents (PTA). As
such, polymer latices and microemulsions formed by non-ionic surfactants were
used. In general, a higher PTA concentration enhances the reaction progress.
The feasibility of catalyst recycling by simple phase separation is shown in
principle. The Rh losses are low in the surfactant system and promising for a
technical approach.
Part of Identifier:
ISSN (print): 2044-4753
DDC-Classification:
540 Chemie
Publication Type:
Wissenschaftlicher Artikel
Also published in:
Catalysis Science & Technology. - 3 (2013), 3, S. 600-605
URL of the Original Publication:
DOI of the Original Publication:
Department/institution:
Biologie, Chemie, Pharmazie
