id,collection,dc.contributor.author,dc.date.accessioned,dc.date.available,dc.date.issued,dc.description.abstract[en],dc.format.extent,dc.identifier.uri,dc.language,dc.rights.uri,dc.subject.ddc,dc.subject[en],dc.title,dc.type,dcterms.accessRights.openaire,dcterms.bibliographicCitation.doi,dcterms.bibliographicCitation.journaltitle,dcterms.bibliographicCitation.number,dcterms.bibliographicCitation.pageend,dcterms.bibliographicCitation.pagestart,dcterms.bibliographicCitation.url,dcterms.bibliographicCitation.volume,dcterms.isPartOf.eissn,refubium.affiliation,refubium.affiliation.other,refubium.resourceType.isindependentpub,refubium.resourceType.provider "efec961e-3b40-4b24-997e-938b4a35525f","fub188/16","Albrecht, Paul Anton||Rupf, Susanne Margot||Sellin, Malte||Schlögl, Johanna||Riedel, Sebastian||Malischewski, Moritz","2022-04-21T13:50:59Z","2022-04-21T13:50:59Z","2022","The oxidation power of the cyanocarbon TCNQ (tetracyano-quinodimethane) can be significantly increased to approximately E = +0.9 V vs. Cp2Fe by coordination of up to four equivalents of the strong fluorinated Lewis acid B(C6F5)3, resulting in a highly reactive but easy-to-use oxidation system. Thianthrene and tris(4-bromophenyl)amine were oxidized to the corresponding radical cations. Dianionic [TCNQ·4 B(C6F5)3]2− was formed upon reduction with two equivalents of ferrocene or decamethylcobaltocene. [TCNQ·4 B(C6F5)3]− and [TCNQ·4 B(C6F5)3]2− are rare cases of redox-active weakly-coordinating anions.","4 Seiten","https://refubium.fu-berlin.de/handle/fub188/34769||http://dx.doi.org/10.17169/refubium-34488","eng","https://creativecommons.org/licenses/by/4.0/","500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften","tetracyano-quinodimethane||cyanocarbon TCNQ||oxidation power","Increasing the oxidation power of TCNQ by coordination of B(C6F5)3","Wissenschaftlicher Artikel","open access","10.1039/D2CC00314G","Chemical Communications","32","4961","4958","https://doi.org/10.1039/D2CC00314G","58","1364-548X","Biologie, Chemie, Pharmazie","Institut für Chemie und Biochemie:::bdaf1c47-f341-464f-b012-0d24067d34b8:::600","no","WoS-Alert"