id,collection,dc.contributor.author,dc.date.accessioned,dc.date.available,dc.date.issued,dc.description.abstract[en],dc.format.extent,dc.identifier.sepid,dc.identifier.uri,dc.language,dc.rights.uri,dc.subject.ddc,dc.subject[en],dc.title,dc.type,dcterms.accessRights.openaire,dcterms.bibliographicCitation.articlenumber,dcterms.bibliographicCitation.doi,dcterms.bibliographicCitation.journaltitle,dcterms.bibliographicCitation.number,dcterms.bibliographicCitation.originalpublishername,dcterms.bibliographicCitation.originalpublisherplace,dcterms.bibliographicCitation.url,dcterms.bibliographicCitation.volume,dcterms.isPartOf.eissn,refubium.affiliation,refubium.affiliation.other,refubium.resourceType.isindependentpub "adce6635-16d0-43c4-b31d-e542130160e8","fub188/16","Brausse, Felix||Bach, Florian||Krečinić, Faruk||Vrakking, Marc J. J.||Rouzée, Arnaud","2021-03-30T07:21:11Z","2021-03-30T07:21:11Z","2020","We report experiments on laser-assisted electron recollisions that result from strong-field ionization of photoexcited I2 molecules in the regime of low-energy electron scattering (<25  eV impact energy). By comparing differential scattering cross sections extracted from the angle-resolved photoelectron spectra to differential scattering cross sections from quantum-scattering calculations, we demonstrate that the electron-scattering dynamics is dominated by a shape resonance. When the molecular bond stretches during the evolution of a vibrational wave packet this shape resonance shifts to lower energies, both in experiment and theory. We explain this behavior by the nature of the resonance wave function, which closely resembles an antibonding molecular orbital of I2.","6 Seiten","80786","https://refubium.fu-berlin.de/handle/fub188/30048||http://dx.doi.org/10.17169/refubium-29790","eng","https://creativecommons.org/licenses/by/4.0/","500 Naturwissenschaften und Mathematik::530 Physik::539 Moderne Physik","Electronic excitation & ionization||Interatomic & molecular potentials||Multiphoton or tunneling ionization & excitation||Scattering theory","Evolution of a Molecular Shape Resonance along a Stretching Chemical Bond","Wissenschaftlicher Artikel","open access","123001","10.1103/PhysRevLett.125.123001","Physical Review Letters","12","American Physical Society","College Park, MD","http://dx.doi.org/10.1103/PhysRevLett.125.123001","125","0031-9007","Physik","Institut für Experimentalphysik:::0e15dd66-95f1-40d5-8307-e68203f86a76:::600","no"