id,collection,dc.contributor.author,dc.date.accessioned,dc.date.available,dc.date.issued,dc.description.abstract[en],dc.format.extent,dc.identifier.uri,dc.language,dc.rights.uri,dc.subject.ddc,dc.subject[en],dc.title,dc.type,dcterms.accessRights.openaire,dcterms.bibliographicCitation.articlenumber,dcterms.bibliographicCitation.doi,dcterms.bibliographicCitation.journaltitle,dcterms.bibliographicCitation.number,dcterms.bibliographicCitation.originalpublishername,dcterms.bibliographicCitation.url,dcterms.bibliographicCitation.volume,dcterms.isPartOf.eissn,refubium.affiliation,refubium.affiliation.other,refubium.resourceType.isindependentpub,refubium.resourceType.provider "43977010-7d2a-431f-9fb3-c79c82517654","fub188/16","Duvinage, Daniel||Lork, Enno||Grabowsky, Simon||Mebs, Stefan||Beckmann, Jens","2020-09-16T06:32:21Z","2020-09-16T06:32:21Z","2020","The reaction of (6-Ph2P-Ace-5-)2P(O)H with (tht)AuCl3 proceeds via elimination of tetrahydrothiophene (tht) and HCl, providing the zwitterionic PPP-pincer complex (6-Ph2P-Ace-5-)2P(O)AuCl2 (1) as yellow crystals. The molecular structure of 1 was established and studied by X-ray crystallography. The electronic structure was computationally analyzed using a comprehensive set of real-space bonding indicators derived from electron and electron-pair densities, providing insight into the relative contributions of covalent and non-covalent forces to the polar-covalent Au–Cl, Au–P, and P–O− bonds; the latter being one of the textbook cases for strongly polarized covalent interactions. Partial spatial complementarity between both bonding aspects is suggested by the electronic properties of the distinctively different Au–Cl bonds.","8 Seiten","https://refubium.fu-berlin.de/handle/fub188/28268||http://dx.doi.org/10.17169/refubium-28018","eng","https://creativecommons.org/licenses/by/4.0/","500 Naturwissenschaften und Mathematik::530 Physik::530 Physik","pincer ligands||secondary phosphine oxide||gold complex||real-space bonding indicators","Synthesis, Structure and Bonding Analysis of the Zwitterionic PPP-Pincer Complex (6-Ph2P-Ace-5-)2P(O)AuCl2","Wissenschaftlicher Artikel","open access","564","10.3390/cryst10070564","Crystals","7","MDPI","https://doi.org/10.3390/cryst10070564","10","2073-4352","Physik","Institut für Experimentalphysik:::0e15dd66-95f1-40d5-8307-e68203f86a76:::600","no","WoS-Alert"