id,collection,dc.contributor.author,dc.date.accessioned,dc.date.available,dc.date.issued,dc.description.abstract[en],dc.format.extent,dc.identifier.sepid,dc.identifier.uri,dc.language,dc.rights.uri,dc.subject.ddc,dc.title,dc.type,dcterms.accessRights.openaire,dcterms.bibliographicCitation,dcterms.bibliographicCitation.doi,dcterms.bibliographicCitation.url,dcterms.isPartOf.issn,refubium.affiliation[de],refubium.mycore.derivateId,refubium.mycore.fudocsId,refubium.resourceType.isindependentpub "3228efb9-a3fd-49d0-b268-5d01fc74c9ad","fub188/16","Sedlmeier, Felix||Netz, Roland R.","2018-06-08T03:42:16Z","2014-03-13T07:48:44.163Z","2012","The temperature-dependent solvation of hydrophobic solutes in water is investigated by largescale molecular dynamics simulations. A simultaneous fit of solvation free energies for spheres and cylinders with radii up to R = 2 nm yields a negative Tolman length on the order of 1 Å at room temperature, equivalent to a spontaneous curvature that favors water droplets over cavities. Pronounced crossover effects of the surface free energy are analyzed in terms of higherorder curvature corrections and water-discreteness effects.","14 S","23113","https://refubium.fu-berlin.de/handle/fub188/15761||http://dx.doi.org/10.17169/refubium-19948","eng","http://publishing.aip.org/authors/web-posting-guidelines","500 Naturwissenschaften und Mathematik::530 Physik","The spontaneous curvature of the water-hydrophobe interface","Wissenschaftlicher Artikel","open access","The Journal of Chemical Physics. - 137 (2012), 13, Artikel Nr. 135102/1-14","10.1063/1.4755753","http://dx.doi.org/10.1063/1.4755753","00219606","Physik","FUDOCS_derivate_000000003234","FUDOCS_document_000000019872","no"